Type 2 Intramolecular N-Acylazo Diels−Alder Reaction: Regio- and Stereoselective Synthesis of Bridgehead Bicyclic 1,2-Diazines
نویسندگان
چکیده
منابع مشابه
The Type 2 Intramolecular Diels-Alder Reaction: Synthesis and Chemistry of Bridgehead Alkenes.
Anti-Bredt alkenes, bicyclic molecules that contain a bridgehead double bond, were for many years regarded as chemical curiosities. The type 2 intramolecular Diels-Alder (IMDA) reaction provides a one-step entry into this fascinating class of molecules. The reaction has made available numerous anti-Bredt alkenes for structural and chemical studies. X-ray crystallography has revealed the magnitu...
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2007
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo070978f